AustralieFrV1, Main, Exploration, bibRecord, 001D50

How to explain microemulsions formed by solvent mixtures without conventional surfactants

Identifieur interne : 001D50 ( Main/Exploration ); précédent : 001D49; suivant : 001D51

How to explain microemulsions formed by solvent mixtures without conventional surfactants

Auteurs : Thomas N. Zemb [France] ; Michael Klossek [Allemagne] ; Tobias Lopian [France, Allemagne] ; Julien Marcus [Allemagne] ; Sebastian Schöettl [Allemagne] ; Dominik Horinek [Allemagne] ; Sylvain F. Prevost [France] ; Didier Touraud [Allemagne] ; Olivier Diat [France] ; Stjepan Mar Elja [Australie] ; Werner Kunz [France, Allemagne]

Source :

Proceedings of the National Academy of Sciences of the United States of America [ 0027-8424 ] ; 2016.

RBID : PMC:4843454

Abstract

Significance

Beginning over 40 y ago, a curious type of microemulsions—as transparent dispersion of two immiscible liquids separated by an interfacial film—at thermodynamic equilibrium has been described as “pre-Ouzo,” “detergentless,” or surfactant-free microemulsions. The experiments in ternary systems containing one hydrotropic cosolvent were ambiguous, and therefore, there was no need to come up with a general theory. Recent evidence obtained by specific deuteration in neutron scattering established the need for the extension of self-assembly theories based on Derjaguin-Landau-Verwey-Overbeck theory (DLVO), bending, or phase transfer energy. Here, we introduce a general free energy expression for weak self-assembly, where solvation effects and entropy compete without the influence of film bending, that explains all experimental results for this class of microemulsions.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4843454

DOI: 10.1073/pnas.1515708113
PubMed: 27044068
PubMed Central: 4843454

Affiliations:

Allemagne, Australie, France

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">How to explain microemulsions formed by solvent mixtures without conventional surfactants</title>
<author><name sortKey="Zemb, Thomas N" sort="Zemb, Thomas N" uniqKey="Zemb T" first="Thomas N." last="Zemb">Thomas N. Zemb</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Klossek, Michael" sort="Klossek, Michael" uniqKey="Klossek M" first="Michael" last="Klossek">Michael Klossek</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lopian, Tobias" sort="Lopian, Tobias" uniqKey="Lopian T" first="Tobias" last="Lopian">Tobias Lopian</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Marcus, Julien" sort="Marcus, Julien" uniqKey="Marcus J" first="Julien" last="Marcus">Julien Marcus</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Schoettl, Sebastian" sort="Schoettl, Sebastian" uniqKey="Schoettl S" first="Sebastian" last="Schöettl">Sebastian Schöettl</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Horinek, Dominik" sort="Horinek, Dominik" uniqKey="Horinek D" first="Dominik" last="Horinek">Dominik Horinek</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Prevost, Sylvain F" sort="Prevost, Sylvain F" uniqKey="Prevost S" first="Sylvain F." last="Prevost">Sylvain F. Prevost</name>
<affiliation wicri:level="1"><nlm:aff id="aff3">European Synchrotron Radiation Facility (ESRF), 38043 Grenoble, CEDEX 9,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Touraud, Didier" sort="Touraud, Didier" uniqKey="Touraud D" first="Didier" last="Touraud">Didier Touraud</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Diat, Olivier" sort="Diat, Olivier" uniqKey="Diat O" first="Olivier" last="Diat">Olivier Diat</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Mar Elja, Stjepan" sort="Mar Elja, Stjepan" uniqKey="Mar Elja S" first="Stjepan" last="Mar Elja">Stjepan Mar Elja</name>
<affiliation wicri:level="1"><nlm:aff id="aff4">Department of Applied Mathematics, Research School of Physics & Engineering,<institution>Australian National University</institution>
, Canberra, ACT 0200,<country>Australia</country>
</nlm:aff>
<country xml:lang="fr">Australie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Kunz, Werner" sort="Kunz, Werner" uniqKey="Kunz W" first="Werner" last="Kunz">Werner Kunz</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">27044068</idno>
<idno type="pmc">4843454</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4843454</idno>
<idno type="RBID">PMC:4843454</idno>
<idno type="doi">10.1073/pnas.1515708113</idno>
<date when="2016">2016</date>
<idno type="wicri:Area/Pmc/Corpus">000493</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000493</idno>
<idno type="wicri:Area/Pmc/Curation">000493</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000493</idno>
<idno type="wicri:Area/Pmc/Checkpoint">000873</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000873</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="wicri:Area/PubMed/Corpus">001F86</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001F86</idno>
<idno type="wicri:Area/PubMed/Curation">001F61</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001F61</idno>
<idno type="wicri:Area/PubMed/Checkpoint">001F61</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001F61</idno>
<idno type="wicri:Area/Ncbi/Merge">003359</idno>
<idno type="wicri:Area/Ncbi/Curation">003359</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">003359</idno>
<idno type="wicri:doubleKey">0027-8424:2016:Zemb T:how:to:explain</idno>
<idno type="wicri:Area/Main/Merge">001D47</idno>
<idno type="wicri:Area/Main/Curation">001D50</idno>
<idno type="wicri:Area/Main/Exploration">001D50</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">How to explain microemulsions formed by solvent mixtures without conventional surfactants</title>
<author><name sortKey="Zemb, Thomas N" sort="Zemb, Thomas N" uniqKey="Zemb T" first="Thomas N." last="Zemb">Thomas N. Zemb</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Klossek, Michael" sort="Klossek, Michael" uniqKey="Klossek M" first="Michael" last="Klossek">Michael Klossek</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lopian, Tobias" sort="Lopian, Tobias" uniqKey="Lopian T" first="Tobias" last="Lopian">Tobias Lopian</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Marcus, Julien" sort="Marcus, Julien" uniqKey="Marcus J" first="Julien" last="Marcus">Julien Marcus</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Schoettl, Sebastian" sort="Schoettl, Sebastian" uniqKey="Schoettl S" first="Sebastian" last="Schöettl">Sebastian Schöettl</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Horinek, Dominik" sort="Horinek, Dominik" uniqKey="Horinek D" first="Dominik" last="Horinek">Dominik Horinek</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Prevost, Sylvain F" sort="Prevost, Sylvain F" uniqKey="Prevost S" first="Sylvain F." last="Prevost">Sylvain F. Prevost</name>
<affiliation wicri:level="1"><nlm:aff id="aff3">European Synchrotron Radiation Facility (ESRF), 38043 Grenoble, CEDEX 9,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Touraud, Didier" sort="Touraud, Didier" uniqKey="Touraud D" first="Didier" last="Touraud">Didier Touraud</name>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Diat, Olivier" sort="Diat, Olivier" uniqKey="Diat O" first="Olivier" last="Diat">Olivier Diat</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Mar Elja, Stjepan" sort="Mar Elja, Stjepan" uniqKey="Mar Elja S" first="Stjepan" last="Mar Elja">Stjepan Mar Elja</name>
<affiliation wicri:level="1"><nlm:aff id="aff4">Department of Applied Mathematics, Research School of Physics & Engineering,<institution>Australian National University</institution>
, Canberra, ACT 0200,<country>Australia</country>
</nlm:aff>
<country xml:lang="fr">Australie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Kunz, Werner" sort="Kunz, Werner" uniqKey="Kunz W" first="Werner" last="Kunz">Werner Kunz</name>
<affiliation wicri:level="1"><nlm:aff id="aff1"><institution>ICSM (Institut de Chimie Séparative de Marcoule), UMR 5257 (Commissariat a l’energie atomique et aux energies alternatives/CNRS/Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier), 30207 Bagnols sur Cèze</institution>
,<country>France</country>
;</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="aff2">Institut für Physikalische und Theoretische Chemie,<institution>Universität Regensburg</institution>
, 93053 Regensburg,<country>Germany</country>
;</nlm:aff>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Proceedings of the National Academy of Sciences of the United States of America</title>
<idno type="ISSN">0027-8424</idno>
<idno type="eISSN">1091-6490</idno>
<imprint><date when="2016">2016</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><title>Significance</title>
<p>Beginning over 40 y ago, a curious type of microemulsions—as transparent dispersion of two immiscible liquids separated by an interfacial film—at thermodynamic equilibrium has been described as “pre-Ouzo,” “detergentless,” or surfactant-free microemulsions. The experiments in ternary systems containing one hydrotropic cosolvent were ambiguous, and therefore, there was no need to come up with a general theory. Recent evidence obtained by specific deuteration in neutron scattering established the need for the extension of self-assembly theories based on Derjaguin-Landau-Verwey-Overbeck theory (DLVO), bending, or phase transfer energy. Here, we introduce a general free energy expression for weak self-assembly, where solvation effects and entropy compete without the influence of film bending, that explains all experimental results for this class of microemulsions.</p>
</div>
</front>
</TEI>
<affiliations><list><country><li>Allemagne</li>
<li>Australie</li>
<li>France</li>
</country>
</list>
<tree><country name="France"><noRegion><name sortKey="Zemb, Thomas N" sort="Zemb, Thomas N" uniqKey="Zemb T" first="Thomas N." last="Zemb">Thomas N. Zemb</name>
</noRegion>
<name sortKey="Diat, Olivier" sort="Diat, Olivier" uniqKey="Diat O" first="Olivier" last="Diat">Olivier Diat</name>
<name sortKey="Kunz, Werner" sort="Kunz, Werner" uniqKey="Kunz W" first="Werner" last="Kunz">Werner Kunz</name>
<name sortKey="Lopian, Tobias" sort="Lopian, Tobias" uniqKey="Lopian T" first="Tobias" last="Lopian">Tobias Lopian</name>
<name sortKey="Prevost, Sylvain F" sort="Prevost, Sylvain F" uniqKey="Prevost S" first="Sylvain F." last="Prevost">Sylvain F. Prevost</name>
</country>
<country name="Allemagne"><noRegion><name sortKey="Klossek, Michael" sort="Klossek, Michael" uniqKey="Klossek M" first="Michael" last="Klossek">Michael Klossek</name>
</noRegion>
<name sortKey="Horinek, Dominik" sort="Horinek, Dominik" uniqKey="Horinek D" first="Dominik" last="Horinek">Dominik Horinek</name>
<name sortKey="Kunz, Werner" sort="Kunz, Werner" uniqKey="Kunz W" first="Werner" last="Kunz">Werner Kunz</name>
<name sortKey="Lopian, Tobias" sort="Lopian, Tobias" uniqKey="Lopian T" first="Tobias" last="Lopian">Tobias Lopian</name>
<name sortKey="Marcus, Julien" sort="Marcus, Julien" uniqKey="Marcus J" first="Julien" last="Marcus">Julien Marcus</name>
<name sortKey="Schoettl, Sebastian" sort="Schoettl, Sebastian" uniqKey="Schoettl S" first="Sebastian" last="Schöettl">Sebastian Schöettl</name>
<name sortKey="Touraud, Didier" sort="Touraud, Didier" uniqKey="Touraud D" first="Didier" last="Touraud">Didier Touraud</name>
</country>
<country name="Australie"><noRegion><name sortKey="Mar Elja, Stjepan" sort="Mar Elja, Stjepan" uniqKey="Mar Elja S" first="Stjepan" last="Mar Elja">Stjepan Mar Elja</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001D50 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001D50 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Asie
   |area=    AustralieFrV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     PMC:4843454
   |texte=   How to explain microemulsions formed by solvent mixtures without conventional surfactants
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:27044068" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a AustralieFrV1

This area was generated with Dilib version V0.6.33.
Data generation: Tue Dec 5 10:43:12 2017. Site generation: Tue Mar 5 14:07:20 2024

Serveur d'exploration sur les relations entre la France et l'Australie

How to explain microemulsions formed by solvent mixtures without conventional surfactants

How to explain microemulsions formed by solvent mixtures without conventional surfactants

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur les relations entre la France et l'Australie
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.